Naphthalocyanine-Based NIR Organic Photodiode: Understanding the Role of Different Types of Fullerenes

In this work, we presented experimental observation on solution-processed bulk heterojunction organic photodiode using vanadyl 2,11,20,29-tetra tert-butyl 2,3 naphthalocyanine (VTTBNc) as a p-type material. VTTBNc is blended with two different acceptors, which are PC₆₁BM and PC₇₁BM, to offer further understanding in evaluating the performance in organic photodiode (OPD). The blend film of VTTBNc:PC₇₁BM with a volumetric ratio of 1:1 exhibits optimized performance in the VTTBNc blend structure with 2.31 × 10⁹ Jones detectivity and 26.11 mA/W responsivity at a -1 V bias. The response and recovery time of VTTBNc:PC₇₁BM were recorded as 241 ms and 310 ms, respectively. The light absorption measurement demonstrated that VTTBNc could extend the light absorption to the near-infrared (NIR) region. The detail of the enhancement of the performance by adding VTTBNc to the blend was further explained in the discussion section.