Emergence of Thorium-Based Polyoxo Clusters as a Platform for Selective X-ray Dosimetry

A brand-new application of thorium-bearing clusters in the field of ionizing radiation detection is exemplified by two novel hexanuclear thorium clusters, Th-bppCOO-1 and Th-bppCOO-2, which incorporate carboxylate-functionalized 2,6-di(pyrazol-1-yl)pyridine ligands. Notably, Th-bppCOO-1 is composed of an unprecedented [Th₆(OH)₄O₄(H₂O)₅]¹²⁺ secondary building unit, the Th₆ core of which is decorated by five H₂O molecules. Furthermore, selective photoluminescence quenching responses of Th-bppCOO-1 and Th-bppCOO-2 toward X-ray over UV radiation have been demonstrated for the first time.