Evaluation of complexing agents in the gel electro-membrane extraction: An efficient approach for the quantification...

In this work, gel electro-membrane extraction (G-EME) combined with flame atomic absorption spectrometry (FAAS) was used for the determination of zinc ions (Zn²⁺) in water samples. For the first time, the effect of the presence of three types of complexing agents such as phenanthroline (Phen), crown ethers (12C4, 15C5, 18C6), and ethylene-diamine-tetra-acetic acid (EDTA) on the extraction efficiency of zinc ions was studied. In addition, the electroendosmosis (EEO) flow as an unwanted actuator was monitored in the presence and absence of complexing agents. By applying 50 V electrical potential across the membrane, the positive charged Zn²⁺ ions were migrated from a donor phase (pH 5.0) through the agarose gel membrane (pH 5.0, containing a complexing agent) into the acceptor phase (pH 3.0). The obtained results showed that the highest extraction recoveries were obtained when crown ethers, especially 1% (w/v) 18C6 was added to the gel membrane. In addition, EEO flow was decreased in the presence of all complexing agents (except EDTA), probably due to the increase in electrical resistance. Using the optimum conditions, the limit of detection (LOD), the limit of quantification (LOQ), and extraction recovery% (ER%) were 5.0 μg L^-1, 15.0 μg L^-1, and 92.5%, respectively. In the end, the applicability of the developed approach was successfully evaluated to determine Zn²⁺ in tap, mineral, and river water samples.