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Synthesis and Characterization of Metallic Janus MoSH Monolayer.

Xi Wan1, EnZi Chen2, Jie Yao1

  • 1Engineering Research Center of IoT Technology Applications (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China.

ACS Nano
|December 6, 2021
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Summary

Researchers synthesized Janus Molybdenum-doped Silicon (MoSH) monolayers using controlled hydrogen plasma. This study details MoSH properties and its potential for mid-infrared Surface Plasmon Resonance (SPR) applications.

Keywords:
JanusKPFMMoS2MoSHMoSSeplasma

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Janus transition-metal dichalcogenides (TMDCs) exhibit unique properties due to asymmetric chalcogen bonding.
  • Existing synthesis methods for Janus TMDCs often overlook intermediate compounds like Janus Molybdenum-doped Silicon (MoSH).
  • Understanding MoSH formation is crucial for controlled synthesis and avoiding material degradation.

Purpose of the Study:

  • To develop a controlled method for synthesizing Janus MoSH monolayers.
  • To investigate the electronic properties of Janus MoSH.
  • To explore the potential of Janus MoSH for device applications, particularly in Surface Plasmon Resonance (SPR).

Main Methods:

  • Controlled hydrogen (H2) plasma treatment for gradual synthesis of Janus MoSH.
  • Time-of-flight secondary ion mass spectrometry (TOF-SIMS) for material characterization.
  • Field-effect transistor (FET) device studies, Kelvin probe force microscopy (KPFM), and density functional theory (DFT) calculations for electronic property investigation.

Main Results:

  • Successful synthesis of Janus MoSH monolayer confirmed by TOF-SIMS.
  • High intrinsic carrier concentration (∼2 × 10^13 cm^-2) and a Fermi level (∼ -4.11 eV) were determined.
  • Demonstrated a pathway for fabricating Janus Molybdenum-Sulfur-Selenium (MoSSe) from MoSH.

Conclusions:

  • A controlled H2 plasma method enables the synthesis of Janus MoSH.
  • Key electronic parameters of Janus MoSH are identified, significant for device applications.
  • The metallicity of 2D Janus MoSH suggests potential for SPR in the mid-infrared spectrum.