Adsorption of Copper (II) from Aqueous Solutions with Alginate/Clay Hybrid Materials

Massive amounts of industrial and agricultural water around the world are polluted by various types of contaminants that harm the environment and affect human health. Alginic acid is a very versatile green polymer used for heavy metal adsorption due to its availability, biocompatibility, low cost, and non-toxic characteristics. The aim of this paper was to prepare new low-cost hybrid composite beads using sodium alginate with treated montmorillonite and kaolin for the adsorption of copper (Cu) cations. Modified and unmodified clays were investigated by studying their morphology and elemental composition, functional groups, and mean particle size and particle size distribution. The characterization of alginate/clay hybrid composite beads was carried out by evaluating surface morphology (by scanning electron microscopy, SEM), crystallinity (by X-ray diffraction, XRD), and point of zero charge (pH_pzc)(Zeta Potential Analyzer). Batch adsorption experiments of alginate/clay hybrid composite beads investigated the effect of metal concentration in the range of 1-4 mg L^-1 on Cu(II) removal, adsorption kinetic for maximum 240 min, and Langmuir and Freundlich adsorption isotherms by using atomic absorption spectrometry. The pseudo-second-order kinetic model best fitted the adsorption for alginate/montmorillonite beads (R² = 0.994), while the diffusion process was predominant for montmorillonite/kaolin beads (R² = 0.985). The alginate/clay hybrid materials best fitted the Langmuir isotherm model.