MXsorption of mercury: Exceptional reductive behavior of titanium carbide/carbonitride MXenes

Two-dimensional (2D) transition metal carbides and nitrides (MXenes) have drawn considerable attention for application in the field of environmental remediation. In this study, we report the simultaneous reductive-adsorption behavior of Ti₃CNT_x for toxic metal ion Hg²⁺ ion in the aqueous phase. 2D Ti₃CNT_x and Ti₃C₂T_x MXene nanosheets were synthesized by exfoliation of Ti₃AlCN and Ti₃AlC₂ MAX phases, respectively. Various characteristics analysis confirmed the successful fabrication of MAX phases and their exfoliation into MXenes. The fabricated MXene nanosheets were used to investigate their Hg²⁺ removal, Hg²⁺ intercalation, and surface interaction mechanism efficiencies. Both MXenes were found to adsorb and reduce a large amount of Hg²⁺. Analytical techniques such as X-ray powder diffraction, field emission transmission electron microscopy, zeta-potential analyses, and X-ray photoelectron spectroscopy were used to investigate the material characteristics and structural changes after uptake of Hg²⁺. The quantitative investigation confirmed the interaction of bimetal and hydroxyl groups with Hg²⁺ using electrostatic interactions and adsorption-coupled reduction. In addition, both MXenes exhibited extraordinary Hg ion removal capabilities in terms of fast kinetics with an excellent distribution coefficient (K_d^Hg) up to 1.36 × 10⁺⁹. Based on batch adsorption results, Ti₃C₂T_x and Ti₃CNT_x exhibited removal capacities of 5473.13 and 4606.04 mg/g, respectively, for Hg²⁺, which are higher than those of previous Hg adsorbents.