Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Composite Masonry Walls01:18

Composite Masonry Walls

1.4K
Composite masonry walls combine multiple wythes of the same or different masonry materials to create a unified structure. These walls feature wythes that are bonded together either through mortar-filled collar joints, grouted spaces, or more commonly, with rigid metal ties and reinforcements, with the use of masonry header units being rare. Metal ties are preferred because they effectively minimize water penetration, as these walls primarily absorb moisture and then release it into the...
1.4K
Space Trusses01:25

Space Trusses

957
A space truss is a three-dimensional counterpart of a planar truss. These structures consist of members connected at their ends, often utilizing ball-and-socket joints to create a stable and versatile framework. The space truss is widely used in various construction projects due to its adaptability and capacity to withstand complex loads.
At the core of a space truss lies the fundamental unit known as the tetrahedron. This structure is composed of six members that form a three-dimensional shape...
957
Types of Building Separation Joints01:23

Types of Building Separation Joints

363
Building separation joints divide large or complex building structures into smaller, discrete units that can move independently. These joints are categorized into three types: volume-change joints, settlement joints, and seismic separation joints.
Volume-change joints address the effects of expansion and contraction due to temperature and moisture variations. They are strategically placed at discontinuities in a building's mass where cracking is most likely and are spaced about 150 to 200...
363
Indeterminate Structure01:18

Indeterminate Structure

1.0K
Indeterminate structures refer to structures where internal forces and reactions cannot be determined using only the equations of static equilibrium.  Indeterminate structures have more unknown forces and reaction forces than equations of static equilibrium that can be used to determine them. Indeterminate structures are often used in engineering to create complex, efficient, and aesthetically pleasing structures. There are various types of indeterminate structures used in engineering and...
1.0K
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

3.1K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
3.1K
Design Example: Maintaining Level of an Embankment01:19

Design Example: Maintaining Level of an Embankment

169
Constructing a roadway embankment over uneven terrain requires precise leveling to ensure stability and proper drainage. Surveyors use a leveling instrument and staff to calculate ground elevations and determine the required fill material at each point along the embankment alignment.The process begins by positioning a leveling instrument near a benchmark with a known elevation. A backsight reading establishes the instrument height, which serves as a reference for subsequent measurements. A...
169

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Electronic Coupling in Cofacial Heterobimetallic AgCu-Porphyrin Dimers: Bioinspired Analogs of Chlorophyll Special Pairs.

Chemistry (Weinheim an der Bergstrasse, Germany)·2026
Same author

PPTMP: An Asymmetric Tetradentate Ligand for Trivalent Lanthanide/Actinide Separation in Nuclear Waste Management.

Inorganic chemistry·2026
Same author

Role of Stereochemistry in Controlling Magnetic Behavior in Polymeric Materials.

Journal of the American Chemical Society·2026
Same author

Cationic Group 13/14/15 Element Chain Compounds with Pnictogen-Donor Ligands.

Inorganic chemistry·2026
Same author

Contrasting single-molecule magnet behaviour in dysprosium and terbium bis(stannolediide) complexes.

Nature chemistry·2026
Same author

A route to asymmetrically substituted secondary phosphines.

Chemical communications (Cambridge, England)·2026
Same journal

3-Methyleneazetidine: a versatile building block for functional and post-modifiable polysulfonamides.

Chemical communications (Cambridge, England)·2026
Same journal

Synthesis of divalent galactosyl and fucosyl spiropyran derivatives for the targeted inhibition of bacterial biofilms.

Chemical communications (Cambridge, England)·2026
Same journal

Emergent cytotoxicity and mitochondrial alterations induced by a heterobimetallic Re(I)/Au(I) complex.

Chemical communications (Cambridge, England)·2026
Same journal

Cyanoacetylation of amines <i>via</i> a traceless cyanoacetyl radical: synthetic access to teriflunomide.

Chemical communications (Cambridge, England)·2026
Same journal

Loading layered double hydroxide nanoarray catalysts on a micro-curved substrate for kinetics-favorable water electrolysis reaction.

Chemical communications (Cambridge, England)·2026
Same journal

Bridging <i>in situ</i> measurements and practical conditions through gas-liquid management for CO/CO<sub>2</sub> reduction.

Chemical communications (Cambridge, England)·2026
See all related articles

Related Experiment Video

Updated: Oct 9, 2025

Structural Design and Manufacturing of a Cruiser Class Solar Vehicle
14:57

Structural Design and Manufacturing of a Cruiser Class Solar Vehicle

Published on: January 30, 2019

14.0K

Triple-decker complexes incorporating three distinct deck architectures.

Xiaofei Sun1, Akhil Kumar Singh1, Ravi Yadav1

  • 1Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe, 76131, Germany. roesky@kit.edu.

Chemical Communications (Cambridge, England)
|December 17, 2021
PubMed
Summary
This summary is machine-generated.

This study explores the reactions of a dilithioplumbole with phosphorus and arsenic compounds. It resulted in novel phospholyl lithium complexes and unique heterotrimetallic triple-decker polypnictogenides.

More Related Videos

Quadruple-Checkerboard: A Modification of the Three-Dimensional Checkerboard for Studying Drug Combinations
11:15

Quadruple-Checkerboard: A Modification of the Three-Dimensional Checkerboard for Studying Drug Combinations

Published on: July 24, 2021

4.9K
Three-Dimensional Printing of a Complex Aortic Anomaly
03:40

Three-Dimensional Printing of a Complex Aortic Anomaly

Published on: November 1, 2018

6.8K

Related Experiment Videos

Last Updated: Oct 9, 2025

Structural Design and Manufacturing of a Cruiser Class Solar Vehicle
14:57

Structural Design and Manufacturing of a Cruiser Class Solar Vehicle

Published on: January 30, 2019

14.0K
Quadruple-Checkerboard: A Modification of the Three-Dimensional Checkerboard for Studying Drug Combinations
11:15

Quadruple-Checkerboard: A Modification of the Three-Dimensional Checkerboard for Studying Drug Combinations

Published on: July 24, 2021

4.9K
Three-Dimensional Printing of a Complex Aortic Anomaly
03:40

Three-Dimensional Printing of a Complex Aortic Anomaly

Published on: November 1, 2018

6.8K

Area of Science:

  • Organometallic Chemistry
  • Main Group Chemistry
  • Coordination Chemistry

Background:

  • Dilithioplumbole complexes offer unique reactivity profiles.
  • Pnictogen precursors like P4 and ferrocene derivatives are key reagents in inorganic synthesis.
  • Heterometallic triple-decker complexes represent an advanced class of coordination compounds.

Purpose of the Study:

  • To investigate the reactivity of a dilithioplumbole with elemental phosphorus (P4) and pentaphosphaferrocene/pentaarsaferrocene.
  • To synthesize and characterize novel organometallic compounds derived from these reactions.
  • To explore the formation of heterotrimetallic triple-decker polypnictogenides.

Main Methods:

  • Reaction of dilithioplumbole with P4, pentaphosphaferrocene, and pentaarsaferrocene.
  • Characterization of products using spectroscopic techniques and X-ray crystallography.
  • Lead-phosphorus exchange reactions.

Main Results:

  • Reaction with P4 yielded a phospholyl lithium complex via lead-phosphorus exchange.
  • Reactions with [Cp*Fe(η5-E5)] (E=P, As) produced the first Pb-Fe-Li heterotrimetallic triple-decker polypnictogenides.
  • These complexes exhibit novel three-deck motifs.

Conclusions:

  • The dilithioplumbole serves as a versatile precursor for novel organometallic structures.
  • This work expands the known diversity of heterometallic triple-decker complexes.
  • The findings contribute to the understanding of pnictogen chemistry and metal-ligand interactions.