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Transmission Infrared Microscopy and Machine Learning Applied to the Forensic Examination of Original Automotive
Francis Kwofie1, Nuwan Undugodage D Perera2, Kaushalya S Dahal1
1Department of Chemistry, 33086Oklahoma State University, Stillwater, OK, USA.
This study used alternate least squares (ALS) and machine learning to analyze automotive paint infrared (IR) spectra, improving forensic examination accuracy and speed. The method successfully identified vehicle makes and assembly plants from paint samples.
Area of Science:
- Forensic Science
- Spectroscopy
- Machine Learning
Background:
- Automotive paint analysis is crucial in forensic investigations.
- Infrared (IR) spectroscopy is a key technique for identifying paint layers.
- Existing methods can be time-consuming and may face challenges with spectral variations.
Purpose of the Study:
- To enhance the accuracy and speed of forensic automotive paint examination.
- To validate the alternate least squares (ALS) procedure for spectral reconstruction of individual paint layers.
- To apply machine learning for classifying vehicle origin based on paint spectra.
Main Methods:
- Alternate least squares (ALS) reconstruction of IR spectra from cross-sectioned automotive paint samples.
- Analysis of spectra using an in-house library and IR microscope, addressing peak shifts with a correction algorithm.
- Application of machine learning algorithms for classification of vehicle manufacturer and assembly plant.
Main Results:
- ALS procedure validated for spectral reconstruction of individual paint layers.
- A correction algorithm successfully mitigated frequency shifts between different IR spectral collection methods.
- Machine learning correctly classified all twenty-six automotive paint samples by vehicle make, model, and matched them to the correct library sample.
Conclusions:
- The combined ALS reconstruction and machine learning approach significantly improves automotive paint analysis.
- This method offers a faster and more accurate alternative for forensic identification of vehicle paint.
- The developed technique has practical applications in identifying vehicle origin from paint evidence.
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