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Updated: Oct 9, 2025

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
Published on: August 17, 2019
Thin-water-film-enhanced TiO2-based catalyst for CO2 hydrogenation to formic acid
Shaoqin Chen1,2, Siyuan Fang2, Zongwei Sun1
1School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China. wangchunling@sjtu.edu.cn.
Abstract:
Carbon dioxide (CO2) hydrogenation can not only mitigate global warming, but also produce value-added chemicals. Herein, we report a novel three-phase catalytic system with an in situ generated and dynamically updated thin water film covered on the noble-metal-free TiO2-based catalyst for highly efficient CO2 hydrogenation, realizing a four-time enhancement compared with that with the catalyst suspended in water. The water film plays dual roles by directly participating in the reaction and removing the produced oxygenates (mainly formic acid) from the catalyst surface by dissolution. These results demonstrate an effective design for CO2 hydrogenation, which will open a new door to three-phase catalysis.
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