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One-step covalent hydrophobic/hydrophilic functionalization of chemically exfoliated molybdenum disulfide nanosheets
Andriana Plantzopoulou1, Anastasios Stergiou1, Martha Kafetzi1
1Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, Athens 11635, Greece. tagmatar@eie.gr.
Abstract:
The covalent functionalization of chemically exfoliated molybdenum disulfide (ce-MoS2) with hydrophobic poly(methyl methacrylate) and hydrophilic poly(acrylic acid) polymers, in a single-step without additives, is presented. The nature of chemical modification and the impact on the structure of ce-MoS2 were spectroscopically investigated. Complexation of Eu3+ was accomplished on grafted polycarboxylate chains on MoS2.
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