Low Molecular Weight Probe for Selective Sensing of PH and Cu²⁺ Working as Three INHIBIT Based Digital Comparator

A novel simple molecular chemosensor 2 was synthesized and examined for pH, cations and anions detection. At pH values higher than 10, probe 2 switches on a green emission where the excited state intramolecular proton transfer (ESIPT) is ceased. Also, the probe absorption spectrum shows a clear pH dependence, and the probe aqueous solution (ethanol/water = 1:2, borate buffer) responds selectively and sensitively through its fluorescence spectrum to the presence of Cu²⁺. Job's plot gave a 2:1 stoichiometry of Probe-2/Cu²⁺ complex, which responds to the presence of S^2- and H₂PO₄^- in aqueous solution (ethanol/water = 1:2, borate buffer) by its absorption and fluorescence spectra. In addition, probe 2 mimics a digital comparator based on three INHIBIT logic gates by different outputs using HO^- and H⁺ as inputs. Moreover, probe 2 also executes AND and NOT TRANSFER logic gates using Cu²⁺ and S^2- as inputs.