Simultaneous adsorption of ammonia and phosphate using ferric sulfate modified carbon/zeolite composite from coal...

Removal of nutrients in water is crucial to control eutrophication. Fly ash has been increasingly used to synthesize zeolite to remove nutrients, but it is still poorly understood about the removal capacity of zeolite synthesized from coal gasification slag (CGS), which has not been well recycled in many countries. In this study, the CGS was acid leached, alkali dissolved, and synthesized to carbon/zeolite composite (C/ZC) under induction by medical stone. After being modified by ferric sulfate, the composite was analyzed for the adsorption of NH₄⁺ and PO₄^3-. Results showed that the maximum adsorption capacity by C/ZC is 5.17 mg/g, but C/ZC has no adsorption capacity of PO₄^3-. The ferric sulfate was used to modify C/ZC to obtain carbon/zeolite composite modified by iron (M-C/ZC). M-C/ZC has a higher specific surface area (348.3 m²/g), and the negatively charge of M-C/ZC can adsorb NH₄⁺ and form Fe-O-P between PO₄^3- and Fe-OH bonds. The maximum adsorption capacity of NH₄⁺ and PO₄^3- by M-C/ZC are 7.44 mg/g and 6.94 mg/g, respectively. The removal efficiency of NH₄⁺ and PO₄^3- are up to 88% and 99% under initial NH₄⁺ (5 mg/L) and PO₄^3- (10 mg/L) concentration. The regeneration capacity of M-C/ZC of NH₄⁺ was stronger than that of PO₄^3-. After three cycles, the regeneration rate of M-C/ZC of NH₄⁺ was still up to 76.96%. Our findings suggest the good application potential of M-C/ZC for removing NH₄⁺ and PO₄^3- from wastewater.