Efficacy study of non-lanthanide small luminescent molecules as gunshot residue indicators

The efficiency of using small, non-lanthanide and readily available molecules was tested as luminescent markers for gunshot residue (GSR) analysis. Three luminophores, namely pyrene (Py), fluorescein (Fl) and a Pt-CNN complex (Pt-C) were used in the present study by using their 5 wt% additives to gunpowder filled in a cartridge followed by firing with a 9 mm pistol. The easy visualization of GSR location, collection of GSR samples followed by their identification through various characterization techniques and the possibility of strategically using these markers as a cost-effective alternative compared to any lanthanide material were evaluated through this work. The comparison of physical mixture of marker and gunpowder and surface soaked gunpowder with the same marker (Py) was also evaluated. Spectroscopic (Optical, Luminescence and Raman), Microscopic, Spectrometric (Mass) and thermal analysis (Differential Scanning Calorimetry, DSC) of the marker, gunpowder and GSR residues implies that both the dyes and gunpowder retains their individual properties and those are merely a physical mixture. Overall, the present study clearly demonstrates that these small organic/metal complex based luminophores are cost effective luminescent marker as compared to lanthanide materials for GSR detection / collection and can be strategically use to track the illegal / unauthorized use of gunpowder.