Bi-Functional Paraffin@Polyaniline/TiO₂/PCN-222(Fe) Microcapsules for Solar Thermal Energy Storage and CO₂...

A novel type of bi-functional microencapsulated phase change material (MEPCM) microcapsules with thermal energy storage (TES) and carbon dioxide (CO₂) photoreduction was designed and fabricated. The polyaniline (PANI)/titanium dioxide (TiO₂)/PCN-222(Fe) hybrid shell encloses phase change material (PCM) paraffin by the facile and environment-friendly Pickering emulsion polymerization, in which TiO₂ and PCN-222(Fe) nanoparticles (NPs) were used as Pickering stabilizer. Furthermore, a ternary heterojunction of PANI/(TiO₂)/PCN-222(Fe) was constructed due to the tight contact of the three components on the hybrid shell. The results indicate that the maximum enthalpy of MEPCMs is 174.7 J·g^-1 with encapsulation efficiency of 77.2%, and the thermal properties, chemical composition, and morphological structure were well maintained after 500 high-low temperature cycles test. Besides, the MEPCM was employed to reduce CO₂ into carbon monoxide (CO) and methane (CH₄) under natural light irradiation. The CO evolution rate reached up to 45.16 μmol g^-1 h^-1 because of the suitable band gap and efficient charge migration efficiency, which is 5.4, 11, and 62 times higher than pure PCN-222(Fe), PANI, and TiO₂, respectively. Moreover, the CO evolution rate decayed inapparently after five CO₂ photoreduction cycles. The as-prepared bi-functional MEPCM as the temperature regulating building materials and air purification medium will stimulate a potential application.