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Updated: Oct 6, 2025

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
Binary Solvent Regulated Architecture of Ultra-Microporous Hydrogen-Bonded Organic Frameworks with Tunable
Xiaojun Ding1, Zeyu Liu1, Yusheng Zhang1
1Collaborative Innovation Center of Advanced Nuclear Energy Technology, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084, China.
Abstract:
A binary solvent synthetic strategy is proposed for the construction of C2 -symmetric molecule-based hydrogen-bonded organic frameworks (HOFs) with permanent ultra-micropores and surface polarization derived from tunable coplanar open oxygen atoms. The activated HOFs BTBA-1 a and PTBA-1 a show highly selective separation of CO2 /N2 with a record high ideal adsorbed solution theory (IAST) selectivity >2000 under ambient temperature and pressure.
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