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Updated: Oct 6, 2025

Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds
Published on: October 18, 2018
Oxidative evolution of Z/E-diaminotetraphenylethylene
Xin Li1, Yongbing Zhuang2, Qichao Ran1
1College of Polymer Science and Engineering, State Key Laboratory of Polymer Material and Engineering, Sichuan University, Chengdu 610065, P. R. China.
Abstract:
We report that Z/E-diaminotetraphenylethylene (Z/E-2NH2-TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution accompanying the rearrangement is explained through quantum theoretical calculation.
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