All-Inorganic Perovskite Solar Cells with Tetrabutylammonium Acetate as the Buffer Layer between the SnO₂ Electron...

All-inorganic CsPbI₃ perovskites have great potential in tandem cells in combination with other photovoltaic devices. However, CsPbI₃ perovskite solar cells (PSCs) still face a huge challenge, resulting in a low power conversion efficiency (PCE) relative to organic-inorganic PSCs. In this work, we introduced tetrabutylammonium acetate (TBAAc) as a buffer layer between the SnO₂ electron-transport layer (ETL) and CsPbI₃ all-inorganic perovskite film interface for the first time. TBAAc not only improved the conductivity of SnO₂ ETL but also formed a 1D TBAPbI₃ layer between the SnO₂ ETL and the 3D CsPbI₃ all-inorganic perovskite film, thereby enhancing the stability and passivating the surface defects of the CsPbI₃ perovskite to fabricate high-efficiency carbon-counter electrode (CE)-based CsPbI₃ solar cells. We fabricated carbon-CE-based hole-transporting layer ( HTL)-free PSCs with an FTO/SnO₂/TBAAc/CsPbI₃/C structure. The open-circuit voltage (V_oc), short circuit current density (J_sc), PCE, and fill factor of the champion CsPbI₃ PSCs simultaneously enhanced to 1.08 V, 17.48 mA/cm², 12.79, and 67.8%, respectively. This PCE is currently one of the high efficiencies reported for the above planar-structured carbon-CE-based CsPbI₃ PSCs to date. Moreover, the optimized device exhibits excellent stability, which retained over 83% of its initial PCE after 350 h. This work provides a facile way of simultaneous optimization of the SnO₂ ETL and the CsPbI₃ perovskite layer to fabricate stable and high-efficiency carbon-CE-based CsPbI₃ PSCs.