Enhancements in Ammonia and Methane from Agricultural Sources in the Northeastern Colorado Front Range Using...

Quantifying ammonia (NH₃) to methane (CH₄) enhancement ratios from agricultural sources is important for understanding air pollution and nitrogen deposition. The northeastern Colorado Front Range is home to concentrated animal feeding operations (CAFOs) that produce large emissions of NH₃ and CH₄. Isolating enhancements of NH₃ and CH₄ in this region due to agriculture is complicated because CAFOs are often located within regions of oil and natural gas (O&NG) extraction that are a major source of CH₄ and other alkanes. Here, we utilize a small research aircraft to collect in situ 1 Hz measurements of gas-phase NH₃, CH₄, and ethane (C₂H₆) downwind of CAFOs during three flights conducted in November 2019. Enhancements in NH₃ and CH₄ are distinguishable up to 10 km downwind of CAFOs with the most concentrated portions of the plumes typically below 0.25 km AGL. We demonstrate that NH₃ and C₂H₆ can be jointly used to separate near-source enhancements in CH₄ from agriculture and O&NG. Molar enhancement ratios of NH₃ to CH₄ are quantified for individual CAFOs in this region, and they range from 0.8 to 2.7 ppbv ppbv^-1. A multivariate regression model produces enhancement ratios and quantitative regional source contributions that are consistent with prior studies.