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Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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In convection, thermal energy is carried by the large-scale flow of matter. Ocean currents and large-scale atmospheric circulation, which result from the buoyancy of warm air and water, transfer hot air from the tropics toward the poles and cold air from the poles toward the tropics. The Earth’s rotation interacts with those flows, causing the observed eastward flow of air in the temperate zones. Convection dominates heat transfer by air, and the amount of available space for the airflow...
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Just as interesting as the effects of heat transfer on a system are the methods by which the heat transfer occur. Whenever there is a temperature difference, heat transfer occurs. It may occur rapidly, such as through a cooking pan, or slowly, such as through the walls of a picnic ice box. So many processes involve heat transfer that it is hard to imagine a situation where no heat transfer occurs. Yet, every heat transfer takes place by only three methods: conduction, convection, and radiation.
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Heat transfer between the human body and its environment occurs through four main mechanisms: conduction, convection, radiation, and evaporation.
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Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
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Anomalous heating in a colloidal system.

Avinash Kumar1, Raphaël Chétrite2, John Bechhoefer3

  • 1Department of Physics, Simon Fraser University, Burnaby, BC V5A 1S6, Canada.

Proceedings of the National Academy of Sciences of the United States of America
|January 26, 2022
PubMed
Summary
This summary is machine-generated.

Researchers observed the inverse Mpemba effect in a colloidal system, where colder initial temperatures led to faster heating. This anomalous heating phenomenon was studied in Brownian particles within a tilted double-well potential.

Keywords:
Fokker–Planck equationfeedback trapsforward Mpemba effectinverse Mpemba effectthermal relaxation

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Area of Science:

  • Thermodynamics
  • Colloidal science
  • Statistical physics

Background:

  • The Mpemba effect describes anomalous heat transfer where hotter water can freeze faster than colder water.
  • The inverse Mpemba effect, a less common phenomenon, describes situations where colder systems heat up faster than warmer ones.
  • Understanding anomalous heat transfer is crucial for various physical and chemical processes.

Purpose of the Study:

  • To experimentally observe and investigate the inverse Mpemba effect in a colloidal system.
  • To analyze the dependence of heating times on initial temperatures in a Brownian particle system.
  • To explore the role of entropic effects in anomalous heating phenomena.

Main Methods:

  • Utilizing a colloidal system with an overdamped Brownian particle.
  • Simulating particle behavior in a tilted double-well potential.
  • Measuring heating times for systems prepared at different initial temperatures.

Main Results:

  • Observed anomalous heating, consistent with the inverse Mpemba effect, in the colloidal system.
  • Found a nonmonotonic relationship between initial temperature and heating time.
  • Demonstrated that entropic effects can weaken the inverse Mpemba effect compared to the usual Mpemba effect.
  • Identified a strong version of anomalous heating where a cold system heats up exponentially faster.

Conclusions:

  • The inverse Mpemba effect is experimentally observable in colloidal systems.
  • Entropic effects play a significant role in modulating the inverse Mpemba effect.
  • The study provides insights into non-equilibrium thermodynamics and anomalous heat transfer mechanisms.