Polyoxometalate-Containing Supramolecular Gels

Supramolecular gels are important soft materials with various applications, which are fabricated through hydrogen bonding, π-π stacking, electrostatic interactions, or host-guest interactions. Introducing functional groups, especially inorganic components, is an efficient strategy to obtain gels with robust architecture and high performance. Polyoxometalates (POMs), as a class of negatively-charged clusters, have defined structures and multiple interaction sites, resulting in their potential as building blocks for constructing POM-containing supramolecular gels. The introduction of POMs into gels not only provides strong driving forces for the formation of gels due to the characteristics of charged cluster and oxygen-rich surface, but also brings new properties sourcing from the unique electronic structures of POMs. Though many POM-containing gels have been reported, a comprehensive review is still absent. Herein, the concept of POM-containing gels is discussed, following with the design strategies and driving forces. To better understand the results in the literature, detailed examples, which are classified into several categories based on the types of organic components, are presented to illustrate the gelation process and gel structures. Moreover, applications of POM-containing gels in energy chemistry, sustainable chemistry, and other aspects are also reviewed, as well as the future developments of this field.