Bis-Heteroleptic Cationic Iridium(III) Complexes Featuring Cyclometalating 2-Phenylbenzimidazole Ligands: A Combined...

In this report, we investigate a new family of cationic iridium(III) complexes featuring the cyclometalating ligand 2-phenylbenzimidazole and ancillary ligand 4,4'-dimethyl-2,2'-bipyridine. Our benchmark complex IrL (L = 2-phenylbenzimidazole) displays emission properties similar to those of the archetypical complex 2,2'-dipyridylbis(2',4'-phenylpyridine)iridium(III) in deaerated CH₃CN (Φ = 0.20, λ_em = 584 nm and Φ = 0.14, λ_em = 585 nm, respectively) but exhibits a higher photoluminescence quantum yield in deaerated CH₂Cl₂ (Φ = 0.32, λ_em = 566 nm and Φ = 0.20, λ_em = 595 nm, respectively) and especially a lower nonradiative constant (k_nr = 6.6 × 10⁵ s^-1 vs k_nr = 1.4 × 10⁶ s^-1, respectively). As a primary investigation, we explored the influence of the introduction of electron-donating and electron-withdrawing groups on the benzimidazole moiety and the synergetic effect of the substitution of the cyclometalating phenyl moiety at the para position with the same substituents. The emission energy displays very good correlation with the Hammett constants of the introduced substituents as well as with ΔE_redox values, which allow us to ascribe the phosphorescence of these series to emanate mainly from a mixed metal/ligand to ligand charge transfer triplet excited state (³M/LLCT*). Two complexes (IrL and IrL) display a switch of the lowest triplet excited state from ³M/LLCT* to ligand centered (³LC*), from the less polar CH₂Cl₂ to the more polar CH₃CN. The observed results are supported by (TD)-DFT computations considering the vibrational contributions to the electronic transitions. Chromaticity diagrams based on the maximum emission wavelength of the recorded and simulated phosphorescence spectra demonstrate the strong promise of our complexes as emitting materials, together with the very good agreement between experimental and theoretical results.