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Updated: Oct 4, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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Synthesis of a π-Extended Azacorannulenophane Enabled by Strain-Induced 1,3-Dipolar Cycloaddition

Xinjiang Zhang1, Marc R Mackinnon2, Graham J Bodwell2

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore, 637371, Singapore.

Angewandte Chemie (International Ed. in English)
|February 11, 2022
PubMed
Summary

Researchers synthesized a novel cyclophane with a nitrogen-containing buckybowl using cycloaddition and palladium catalysis. This π-extended azacorannulenophane displays unique structural and electronic properties due to its curved polycyclic aromatic system.

Keywords:
AzacorannulenesCycloadditionsCyclophanesPyrenophanesStructure Elucidation

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