Treated activated carbon as a metal-free catalyst for effectively catalytic reduction of toxic hexavalent chromium

In this work, activated carbon treated in N₂ atmosphere, as a non-metallic catalyst, exhibits excellent catalytic performance in reduction of Cr (VI) to Cr (III) using HCOOH as the reducing agent at room temperature. A series of characterizations and control experiments were carried out to deduce the possible reaction mechanism. The results showed that the improved catalytic performance can be attributed to the enhanced graphitization degree and basic sites such as pyrone-like, which favor electron transferring and activation of reactant. The reaction rate constant observed herein for the C-800 was 22 and 6 times more than that for C-0 and Pd/C catalyst, respectively. In addition, C-800 showed good recycle performance, and no loss of activity was observed after 5 cycles. This study broadens the application of nonmetallic catalyst and provides an easy-available and cost-effective catalytic material for removing toxic Cr (VI).