Phosphogermanate Crystal: A New Ultraviolet-Infrared Nonlinear Optical Crystal with Excellent Optical Performances

The phase matching ability is a key factor for nonlinear optical crystals to realize coherent output. Herein, a new design strategy combining ultraviolet and infrared functional groups into a ferroelectric was put forward. Thus, a phosphogermanate crystal, KGeOPO₄, was designed and studied. It exhibits a wide transparency window (0.22-9.70 μm), a strong second harmonic generation response (5× KH₂PO₄), a high laser-induced damage threshold (1.61 GW/cm²), and the typical ferroelectricity (coercive field ∼ 9.8 kV/cm and remnant polarization ∼7.6 μC/cm²). In the infrared region, it could realize coherent output by the birefringence phase matching method, while it could generate ultraviolet coherent lights by the quasi-phase matching technique. Therefore, this work designs a promising ultraviolet-infrared nonlinear optical crystal and provides a new perspective for exploring nonlinear optical crystals.