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Updated: Oct 3, 2025

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
[Co2@(Ge17Ni)]4-: the first edge-sharing double-cage endohedral germanide
Hong-Lei Xu1, Lei Qiao1, Zhong-Ming Sun1
1State Key Laboratory of Elemento-Organic Chemistry, Tianjin Key Lab of Rare Earth Materials and Applications, School of Material Science and Engineering, Nankai University, Tianjin 300350, China. sunlab@nankai.edu.cn.
Abstract:
We report here a new double-cage endohedral Ge cluster, [Co2@(Ge17Ni)]4-, fused through two [Co@(Ge9Ni)] moieties with a shared Ni-Ge edge. This ternary Co-Ge-Ni species not only represents the first double-cage example of an 18-vertex Zintl cluster, but also fills in the missing link of the edge fusion model in the double-cage systems.
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