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Updated: Oct 3, 2025

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin
Published on: July 23, 2016
Support effects of metal-organic frameworks in heterogeneous catalysis
1Department of Applied Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
Abstract:
Catalytic support effects have been widely studied as a key factor for creating highly active heterogeneous catalysts with limited amounts of rare metal elements. Recently, support effects of metal-organic frameworks (MOFs) started to be investigated using their wide variety in pore size, electronic state, and selective adsorption property. Three types of support effects, namely molecular sieving, charge transfer, and substrate adsorption effects, have been reported on composite catalysts of metal nanoparticles supported on MOFs (M/MOFs). The current reports on heterogeneous catalysis in M/MOFs clearly demonstrated that both catalytic activity and product selectivity can be drastically enhanced and modulated by MOF supports through these support effects, and that application of MOFs as the supports is beneficial for creating novel high performance catalysts with metal nanoparticles. This minireview summarizes the catalytic properties and support effects observed on M/MOFs.
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