Related Experiment Video
Updated: Oct 3, 2025

Spark Plasma Sintering Apparatus Used for the Formation of Strontium Titanate Bicrystals
Published on: February 9, 2017
Alignment of strontium hexaferrite, by cold compaction of anisotropic non-magnetically interacting crystallites
Jack Thomas-Hunt1,2, Amalie Povlsen1, Harikrishnan Vijayan1
1Department of Chemistry & iNANO, Aarhus University, Aarhus C-8000, Denmark. mch@chem.au.dk.
Abstract:
Cold compacted, anisotropic shaped non-magnetically interacting precursors are used to achieve aligned strontium hexaferrites. The simple process of dry mixing platy hematite and/or rod-like goethite with strontium carbonate removes the need for external magnetic fields or high temperatures during compaction to assist in alignment. The calcined strontium hexaferrite pellets all displayed preferred orientation and high levels of phase purity (>99 wt%). The mix of goethite and strontium carbonate achieved the highest degree of magnetic alignment with Mr/Ms reaching 0.83(1) obtained by vibrating sample magnetometry. The magnetic data were supported by examining crystallographic alignment using powder X-ray diffraction as well as 2D texture synchrotron analysis.
More Related Videos
08:55Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
08:00Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Related Concept Videos
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Lattice Centering and Coordination Number
Types of Unit Cells
Imagine taking a large number of identical...