Related Experiment Video
Updated: Oct 2, 2025
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
An asymmetric Pt diimine acetylide complex providing unique luminescent multinuclear sandwich complexes with Cu salts
Shinnosuke Horiuchi1, Hirotaka Hiroiwa1, Eri Sakuda1
1Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi, Nagasaki, 852-8521, Japan. shoriuchi@nagaaki-u.ac.jp.
Abstract:
The formation and photophysical properties of two types of sandwich complexes supported by asymmetric Pt complex units having two different acetylide moieties are reported. The asymmetric Pt complex unit was obtained via acetylide metathesis reaction between two types of symmetric Pt complexes. The reversible acetylide exchange reaction was effectively suppressed by the incorporation of Cu ions to give unique chiral Pt4Cu3 and achiral Pt2Cu4Br4 sandwich complexes. The sandwich complexes exhibited moderate photoluminescence in the solid state, and their photophysical properties depended on the sandwich structures. These results suggest that asymmetric Pt complex units can give remarkable assembled structures by the concerted effect of labile coordination bonds and weak noncovalent interactions.
More Related Videos
Related Concept Videos
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
Valence Bond Theory
Complexometric Titration: Ligands
Complexation Equilibria: The Chelate Effect
EDTA: Chemistry and Properties
Stereoisomerism
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...

