Looking deep into C-H functionalization: the synthesis and application of cyclopentadienyl and related metal
Guilherme A M Jardim1,2, Renato L de Carvalho1, Mateus P Nunes1
1Institute of Exact Sciences, Department of Chemistry, Federal University of Minas Gerais - UFMG, Belo Horizonte, 31270-901, MG, Brazil. eufranio@ufmg.br.
Abstract:
Metal catalyzed C-H functionalization offers a versatile platform for methodology development and a wide variety of reactions now exist for the chemo- and site-selective functionalization of organic molecules. Cyclopentadienyl-metal (CpM) complexes of transition metals and their correlative analogues have found widespread application in this area, and herein we highlight several key applications of commonly used transition-metal Cp-type catalysts. In addition, an understanding of transition metal Cp-type catalyst synthesis is important, particularly where modifications to the catalyst structure are required for different applications, and a summary of this aspect is given.
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