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Updated: Oct 2, 2025

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
Porphyriynes: 18-π-Conjugated Macrocycles Incorporating a Triple Bond
Fei Hao1,2, Tian Zhang1, Donghai Yu2
1Shandong Provincial Key Laboratory of Molecular Engineering, Qilu University of Technology-Shandong Academy of Science, Ji'nan 250353, China.
Abstract:
Tetraphenylporphyriyne (Pyne1), a novel porphyrin analogue with a C≡C bond incorporated into an 18-π-conjugated system, has been created via cleavage of the N-confused pyrrolic ring in Ag(III) N-confused tetraphenylporphyrin. The structure of Pyne1 was confirmed by X-ray crystallography and 1H NMR, IR, and UV-vis spectroscopy. The mechanism of cleavage of the N-confused pyrrolic ring was investigated by theoretical calculations. The successful synthesis of other Pynes indicated the generality of this protocol.
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