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Toward Optimized Charge Transport in Multilayer Reduced Graphene Oxides.

Mustafa Neşet Çınar1, Aleandro Antidormi2, Viet-Hung Nguyen3

  • 1Department of Materials Science and Engineering, Izmir Institute of Technology, 35430 Urla, Izmir, Turkey.

Nano Letters
|March 1, 2022
PubMed
Summary

Understanding charge conduction in multilayer reduced graphene oxides (rGO) is key for graphene composites. This study reveals how interlayer interactions and film thickness impact electronic flow, offering insights for material optimization.

Keywords:
charge transportdisordered van der Waals thin filmsinterlayer transportmultilayer transport scaling lawquantum transportreduced graphene oxides

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Computational Chemistry

Background:

  • Multilayer reduced graphene oxides (rGO) are crucial for graphene-based composites.
  • Disorder from synthesis methods complicates charge conduction understanding.
  • The role of interlayer interactions in electronic flow is unclear.

Purpose of the Study:

  • To elucidate charge conduction mechanisms in multilayer rGO.
  • To investigate the impact of interlayer interactions on electronic transport.
  • To explain transport scaling laws in rGO films.

Main Methods:

  • Development of a multiscale computational approach.
  • Integration of first-principles calculations with large-scale transport simulations.
  • Comparison of theoretical predictions with experimental data.

Main Results:

  • Transport scaling laws in multilayer rGO were unraveled.
  • Diffusion was found to worsen with increasing film thickness.
  • Contacted films showed thickness-independent conduction driven by interlayer hopping when mean free path was short.

Conclusions:

  • Interlayer hopping becomes dominant in contacted films under specific conditions.
  • The findings provide a basis for optimizing graphene composites.
  • Improved electrical conduction in graphene-based materials is achievable through understanding these mechanisms.