Cooperative approaches in catalytic hydrogenation and dehydrogenation
Michael A Stevens1, Annie L Colebatch1
1Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia. annie.colebatch@anu.edu.au.
Abstract:
Metal-ligand cooperativity (MLC) is an established strategy for developing effective hydrogenation and dehydrogenation catalysts. Metal-metal cooperativity (MMC) in bimetallic complexes is not as well understood, and to date has had limited implementation in (de)hydrogenation. Herein we use (de)hydrogenation processes as a platform to examine modes of cooperativity, with a particular focus on catalytic mechanisms. We investigate how lessons learnt from the extensive development of metal-ligand cooperative catalysts can aid the ongoing development of metal-metal cooperative catalysts.
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