Hydroxylamine mediated Fenton-like interfacial reaction dynamics on sea urchin-like catalyst derived from spent...

Herein, we converted spent LiFePO₄ battery to the sea urchin-like material (SULM) with a highly efficient and environment-friendly method, which can contribute to building a zero-waste city. With SULM as a Fenton-like catalyst, a highly-efficient degradation process was realized for organic pollutants with interface and solution synergistic effect. In our SULM+NH₂OH+H₂O₂ Fenton-like system, NH₂OH can effectively promote the interface iron (Fe(Ⅲ)/Fe(Ⅱ)) and solution iron (Fe(Ⅲ)/Fe(Ⅱ)) redox cycle, thus promoting the generation of reactive oxygen species (ROS). However, the ROS generation process and organic pollutants degradation pathway with the presence of NH₂OH remains a puzzle. Here the detailed ROS generation mechanism and pollutants degradation pathway have been illustrated carefully based on experimental exploration and characterization. Therein, hydroxyl radicals (·OH) and singlet oxygen (¹O₂) are the main ROS for oxidizing and degrading organic pollutants. Notably, ¹O₂ can be converted from superoxide radicals (·O₂) in SULM+NH₂OH+H₂O₂ system. This study not only demonstrates the strategy of "trash-to-treasure" and "waste-to-control-waste" to simultaneously reduce the hazardous release from industrial solid waste and organic wastewater, it also provides new mechanistic insights for NH₂OH mediated Fenton-like redox system.