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Online rapid total nitrogen detection method based on UV spectrum and spatial interval permutation combination

Jingxuan Geng1, Chunhua Yang1, Lijuan Lan1

  • 1School of Automation, Central South University, 410083 Changsha, China.

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|March 6, 2022
PubMed
Summary

This study introduces a new method for rapid total nitrogen (TN) detection in surface water using UV spectroscopy. The technique significantly reduces analysis time to 5 minutes with high accuracy, aiding water protection efforts.

Keywords:
Automatic optical inspectionMultivariate calibrationSpatial–temporal relationshipTotal nitrogen (TN) rapid detectionWavelength selection

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Area of Science:

  • Environmental Chemistry
  • Analytical Chemistry
  • Spectroscopy

Background:

  • Total nitrogen (TN) is a key indicator of surface water eutrophication.
  • Traditional TN detection methods are time-consuming due to tedious oxygen digestion processes.
  • Rapid and accurate TN detection is crucial for effective surface water protection.

Purpose of the Study:

  • To develop a novel online rapid TN detection method for surface water.
  • To overcome the limitations of traditional methods by reducing detection time.
  • To improve the speed and accuracy of monitoring water quality.

Main Methods:

  • Utilized ultraviolet (UV) spectroscopy to observe nitrogenous substance transformations during early oxygen digestion.
  • Developed a new wavelength selection algorithm, spatial interval permutation combination population analysis (siPCPA), considering spatial-temporal spectral relationships.
  • Applied the method to real surface water samples from Houhu Lake, Changsha, China.

Main Results:

  • The proposed method enables TN concentration prediction using spectral variations in the early stages of oxygen digestion.
  • The siPCPA algorithm effectively selects informative variables from three-dimensional spectra.
  • Practical application demonstrated TN determination in 5 minutes with a relative error of less than 5%.

Conclusions:

  • The novel online rapid TN detection method significantly reduces analysis time.
  • The developed siPCPA algorithm enhances spectral data analysis for accurate TN prediction.
  • This method offers a fast, accurate, and practical solution for surface water quality monitoring and eutrophication assessment.