Superfast-Expanding Porous Hydrogels: Pushing New Frontiers in Converting Chemical Potential into Useful Mechanical...

Superabsorbent polymer gels can absorb large amounts of water (100-1000× their dry weight). For the past 50 years, many scientists such as de Gennes have proposed to extract mechanical work from gel expansion/contraction, which could pave the way for "artificial muscles". However, slow rates of gel expansion have limited these efforts: macroscale (∼cm) gels take over 24 h to expand to their equilibrium size. Gels can be made to expand faster if their characteristic length scale is reduced, e.g., by making a macroscopic gel porous. Still, gels that are both superabsorbent and able to expand rapidly have not yet been realized. Here, we create gels at the macroscale (∼cm or larger) that are porous, highly robust, superabsorbent and expand much faster than any gels thus far. Our approach involves the in situ foaming of a monomer solution (acrylic acid and acrylamide) using a double-barreled syringe that has acid and base in its two barrels. Gas (CO₂) is generated at the mixing tip of the syringe by the acid-base reaction, and gas bubbles are stabilized by an amphiphilic polymer in one of the barrels. The monomers are then polymerized by ultraviolet (UV) light to form the gel around the bubbles, and the material is dried under ambient conditions to give a porous solid. When this dry gel is added to water, it absorbs water at a rate of 20 g/g·s until an equilibrium is achieved at ∼300× its weight. In the process, each gel dimension increases by ∼20%/s until its final dimensions are more than 3× larger. Such rapid and appreciable expansion can be easily observed by the eye, and remarkably, the swollen gel is robust enough to be picked up by hand. SEM images reveal a porosity of >90% and an interconnected network of pores. The gels are responsive to pH, and a full cycle of expansion (in regular water) and contraction (at pH 10 or in ethanol) can be completed within about 60 s. We use gel expansion to rapidly lift weights against gravity, resulting in ∼0.4 mJ of work being done over 40 s, which translates to a power density of 260 mW/kg. This ability to harness the chemical potential energy from the gel to do useful mechanical work could enable new designs for mechano-chemical engines─and potentially for artificial muscles.