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Water-Based Highly Stretchable PEDOT:PSS/Nonionic WPU Transparent Electrode.

Youngno Kim1, Sinseok Yoo2, Jung-Hyun Kim2

  • 1KIURI Institute, Yonsei University, 50 Yonsei-ro, Seodaemoon-gu, Seoul 03722, Korea.

Polymers
|March 10, 2022
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Summary

Highly stretchable transparent electrodes were created by blending Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) with waterborne polyurethane (WPU). These electrodes maintain performance even when stretched up to 500%.

Keywords:
PEDOT:PSSstretchable electronicstransparent electrodeswaterborne polyurethane

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Area of Science:

  • Materials Science
  • Polymer Science
  • Conducting Polymers

Background:

  • Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) offers high conductivity and water dispersibility.
  • Improving the stretchability of PEDOT:PSS-based electrodes is crucial for flexible electronics.

Purpose of the Study:

  • To enhance the mechanical stretchability of PEDOT:PSS transparent electrodes.
  • To develop stretchable electrodes for applications like alternating current electroluminescence (ACEL) devices.

Main Methods:

  • Blending PEDOT:PSS with nonionic waterborne polyurethane (WPU).
  • Coating the composite onto a thermoplastic polyurethane (TPU) film substrate.
  • Characterizing electrical properties, sheet resistance, and mechanical stretchability.
  • Fabricating a stretchable ACEL device using the developed electrodes.

Main Results:

  • The composite film with 2.0 wt% WPU demonstrated excellent stretchability, up to 400% without surface damage.
  • Good adhesion was achieved between the WPU-based electrodes and the TPU substrate due to polyester groups.
  • The fabricated ACEL device maintained its luminance at 500% strain.

Conclusions:

  • Blending PEDOT:PSS with WPU significantly improves electrode stretchability while maintaining electrical performance.
  • The WPU/PEDOT:PSS composite is a promising material for stretchable transparent electrodes in flexible electronic devices.
  • The developed electrodes enable the creation of highly stretchable ACEL devices.