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Properties of Organometallic Compounds

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

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Updated: Sep 30, 2025

Synthesis of a Water-soluble Metal–Organic Complex Array

Synthesis of a Water-soluble Metal–Organic Complex Array

Published on: October 8, 2016

Metal-organic cycle-based multistage assemblies.

Yan Sun¹, Wei Tuo¹, Peter J Stang¹

¹Department of Chemistry, University of Utah, Salt Lake City, UT 84112.

Proceedings of the National Academy of Sciences of the United States of America

|March 17, 2022

Summary

This summary is machine-generated.

Researchers explored how coordination bonds in metal–organic cycles (MOCs) influence suprastructure formation. The coordination linker is key to controlling the shape and size of these advanced MOC materials.

Keywords:

metal–organic cycle (MOC)multilevel ordering suprastructures (MOS)multistage assembly

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Synthesis and Characterization of Functionalized Metal-organic Frameworks

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Area of Science:

Materials Science
Supramolecular Chemistry
Coordination Chemistry

Background:

Material properties depend on chemical composition and structure.
Functional materials utilize biomolecules or synthetic molecules.
Noncovalent bond-based assembly is less understood than covalent assembly.

Purpose of the Study:

Investigate the influence of coordination bonds on metal–organic cycle (MOC) conformation.
Understand how coordination bonds affect the topology of MOC multilevel ordered materials.
Determine the role of coordination linkers in tuning MOC suprastructure properties.

Main Methods:

Utilized three distinct metal–organic cycles (MOCs).
Analyzed the impact of coordination bonds on bimetallacycle conformation.
Examined the relationship between coordination linkers and suprastructure topology.

Main Results:

Coordination bonds significantly influence bimetallacycle conformation.
Differences in coordination bonds lead to varied MOC multilevel ordered material topologies.
The isophthalate-Pt-pyridine coordination linker effectively tunes MOC suprastructure shape and size.

Conclusions:

Coordination bonds are critical in directing the self-assembly of MOCs.
Tailoring coordination linkers offers precise control over supramolecular architecture.
This study advances the understanding of noncovalent bond-based multistage assembly in functional materials.