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Updated: Sep 29, 2025

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Visible Light-Induced Hydrosilylation of Electron-Deficient Alkenes by Iron Catalysis
Ling Ding1, Kaikai Niu1, Yuxiu Liu1
1State Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Frontiers Science Center for New Organic Matter, Nankai University, Tianjin, 300071, P. R. China.
Abstract:
Herein, we reported a method for iron-catalyzed, visible-light-induced hydrosilylation reactions of electron-deficient alkenes to produce value-added silicon compounds. Alkenes bearing functional groups with different steric properties were suitable substrates, as were derivatives of structurally complex natural products. Mechanistic studies showed that chlorine radicals generated by iron-catalyzed ligand-to-metal charge transfer in the presence of lithium chloride promoted the formation of silyl radicals.
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