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Radical boron migration of allylboronic esters

Xiangzhang Tao1, Shengyang Ni1, Lingyu Kong1

  • 1State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University Nanjing 210023 China yiwang@nju.edu.cn.

Chemical Science
|March 21, 2022
PubMed
Summary

This study introduces a new photocatalyzed reaction for allylboronic esters, enabling boron atom migration across the carbon skeleton. This process efficiently creates functionalized alkyl boronates with diverse applications.

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