Efficient naphthalene degradation in FeS₂-activated nano calcium peroxide system: Performance and mechanisms

Naphthalene (NAP) has received increasing concern due to frequent detection in groundwater and harm to humans. In this study, FeS₂ was selected as a novel catalyst to activate nano calcium peroxide (nCP) for NAP degradation. Batch experiments were conducted in a 250 mL glass reactor containing 0.1 mM NAP solution to investigate the effect of reagents dosage, pH, air conditions (with or without N₂ purge), and different solution matrixes on NAP degradation. Scavenging tests, electron paramagnetic resonance (EPR) spectrum, and radical probe tests were conducted to identify the main radicals. Results indicated that over 96% NAP was removed in a wide pH range (3.0-9.0) within 180 min at optimal dosage of nCP = 1.0 mM and FeS₂ = 5.0 g L^-1 in nCP/FeS₂ system. Aerobic condition was more beneficial to NAP degradation and the system could tolerate complex solution conditions. Moreover, HO• was determined to be responsible for NAP degradation. NAP degradation intermediates were detected by gas chromatography-mass spectrometry (GC-MS) and the possible degradation pathways were revealed. Finally, the efficient degradation of other organic pollutants confirmed the broad-spectrum reactivity of the nCP/FeS₂ system. Overall, these findings strongly demonstrated the potential applicability of nCP/FeS₂ system in remediating organic contaminated groundwater.