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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Stable Au(I) catalysts for oxidant-free C-H Functionalization with Iodoarenes

R Tyler Mertens1, Charles E Greif1, James T Coogle1

  • 1Department of Chemistry, University of Kentucky, Lexington, KY 40506 USA.

Journal of Catalysis
|April 4, 2022
PubMed
Summary

Researchers developed new gold(I) catalysts for oxidant-free C-H functionalization, enabling biaryl synthesis without external oxidants. This breakthrough overcomes limitations in gold-catalyzed cross-coupling reactions.

Keywords:
C-H activationOxidative additiongold catalysistricoordinate gold

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