Efficient purification of tetracycline wastewater by activated persulfate with heterogeneous Co-V bimetallic oxides

The persistence and wide dispersion of antibiotics have a severe impact on the ecological environment. Developing an effective method with universal applicability to remove pollutants is pretty necessary. Herein, a bimetallic oxides (Co₃V₂O₈) heterogeneous material was successfully prepared and used to activate the persulfate (PS) for purification of tetracycline (TC) wastewater. By exploring the reaction conditions and influencing factors, the removal rate of 50 mg⋅L^-1 TC reached 87.1% by Co₃V₂O₈/PS system, and the reaction rate constant was up to 0.0271 min^-1. As a highly efficient catalyst for the activation of PS, Co₃V₂O₈/PS system produces radicals of SO₄^•-, •OH, •O₂^- and ¹O₂ in the reaction process due to the Co(II) and V(IV) exchange electrons with S₂O₈^2- and O₂. Simultaneously, the internal electron exchange occurs between Co(II)/Co(III) and V(IV)/V(V), which stabilizes the content of Co(II) and V(IV). This work provides a novel activator for PS activation to degrade contaminants and contributes to a better understanding of the PS activation mechanism by transition compound.