In situinvestigation on melting characteristics of 1D SnCu alloy nanosolder

Nanosoldering can bond various nanomaterials together or connect them with electrodes to form electrical contacts, thus assembling these nanomaterials into functional nanodevices; it is believed to be a promising interconnection technique due to its flexibility, controllability and crucial advantage of avoiding detrimental effects on the nano-objects. In this technique, molten solder as a filler material is introduced between the objects to be joined to form a reliable bond, in which the nanosolder reflow melting is a crucial prerequisite for successful nanosoldering. This work focuses on studying the melting characteristics of one-dimensional 97Sn3Cu nanosolder with low-cost, prominent electrical property and high mechanical reliability, aiming to promote its applications in nanosoldering. The reflow melting of an individual nanosolder has been dynamically observed byin situheating holder in transmission electron microscopy, where the obtained reflow temperature (530 °C) is much higher than its melting temperature (220.4 °C) because of the external oxide layer confinement. Furthermore, the size-dependent melting temperature of nanosolders with various diameters (20-300 nm) has been investigated by both differential scanning calorimetry and theoretical calculation, revealing that the melting temperature decreases as the diameter goes down, especially for the nanosolders in the sub 80 nm range, where the value decreases significantly. The experimental results are in good agreement with the theoretical predictions. These results pointed out here can be readily extended to other nanosolders.