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Individual iron(iii) glycerolate: synthesis and characterisation
Tat'yana G Khonina1, Elena Yu Nikitina1, Alexander Yu Germov2
1Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch Yekaterinburg 620108 Russia khonina@ios.uran.ru.
Abstract:
Iron(ii) and iron(iii) salts of strong acids form iron glycerolates on heating at 180 °C with glycerol in the presence of an equivalent amount of alkali. Individual iron(iii) glycerolate was obtained for the first time. When Fe3O4 magnetic nanoparticles were heated with glycerol, an iron(iii) glycerolate shell was formed on their surface.
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