Fe₃O₄-Mg(OH)₂ nanocomposite as a scavenger for silver nanoparticles: Rational design, facile synthesis, and enhanced...

Silver nanoparticles (AgNPs) are considered as emerging contaminants because of their high toxicity and increasing environmental impact. Removal of discharged AgNPs from water is crucial for mitigating the health and environmental risks. However, developing facile, economical, and environment-friendly approaches remains challenging. Herein, an Fe₃O₄-Mg(OH)₂ nanocomposite, as a novel magnetic scavenger for AgNPs, was prepared by loading Fe₃O₄ nanoparticles on Mg(OH)₂ nanoplates in a one-pot synthesis. Batch removal experiments revealed that the maximum removal capacities for the two model AgNPs (citrate- or polyvinylpyrrolidone-coated AgNPs) were 476 and 442 mg/g, respectively, corresponding to partition coefficients 8.03 and 4.89 mg/g/μM. Removal feasibilities over a wide pH range of 5-11 and in real water matrices and scavenger reusability with five cycles were also confirmed. Both Fe₃O₄ and Mg(OH)₂ components contributed to the removal; however, their nanocomposites exhibited an enhanced performance because of the high specific surface area and pore volume. Chemical adsorption and electrostatic attraction between the coatings on the AgNPs and the two components in the nanocomposite was considered to be responsible for the removal. Overall, the facile synthesis, convenient magnetic separation, and high removal performance highlight the great potential of the Fe₃O₄-Mg(OH)₂ nanocomposite for practical applications.