Mn₃O₄@polyaniline nanocomposite with multiple active sites to capture uranium(VI) and iodide: synthesis, performance,...

A major challenge for radioactive wastewater treatment and associated environmental remediation is how to simultaneously remove cationic and anionic radionuclides. Herein, a series of Mn₃O₄@polyaniline (Mn₃O₄@PANI) nanocomposites were successfully prepared and used to remove U(VI) and I^- from aqueous solution, two highly concomitant species in nuclear pollution settings. Batch adsorption experiments reveal that the component Mn₃O₄ is predominantly responsible for U(VI) removal, but PANI for I^-. The nanocomposite with 24.2 wt% Mn₃O₄ possesses high removal percentages (> 85%) either for U(VI) or I^- over a wide pH range, fast removal kinetics, and excellent adsorption selectivity at high concentrations of competing ions. Benefiting from the contributions of the two components and the high adsorption affinities, the nanocomposite achieves the simultaneous removal to coexisting U(VI) and I^-, with a maximum adsorption capacity 102.6 mg/g for U(VI) and 126.1 mg/g for I^-. X-ray photoelectron spectroscopy (XPS) results reveal that the U(VI) adsorption occurs via coordination bonding with Mn-O, -NH- , and =N- groups in the nanocomposite, whereas I^- adsorption proceeds mainly through I anionic species exchange with Cl^- and interactions with π-bonds in PANI, as well as the electrostatic attraction onto Mn₃O₄. Considering the excellent performance and multiple active sites, the Mn₃O₄@PANI nanocomposite is promising to remove practical radioactive U(VI) and I^-.