Gas sensing behavior of metal-catecholates based MOFs

We report on the usability aspect of triphenylene ligand-based metal-organic frameworks (MOF) as the potential gas sensing element in chemiresistive devices. Among various possibilities, we explored mono-metallic (Nickel-based) and bi-metallic (Nickel and copper-based) in room temperature gas sensing. Our investigations suggest that the chemiresistive device based on nickel catecholate MOFs were highly sensitive to ethyl alcohol gas in the concentration range of 5-100 ppm with decent sensing parameters such as response time, recovery time, repeatability, stability, etc. We also investigated bimetallic (Nickel and copper) catecholate based MOFs in gas sensing with different metallic content ratios (Cu: Ni:: 60:40 and 40:60). We found that the 1D Cu_0.6Ni_0.4-CAT nanostructures-based gas sensor to be selective towards H₂gas (0.2-7 ppm) at room temperature. We further explored the gas sensing abilities of Cu_0.4Ni_0.6-CAT based devices, and we found them to be selective towards NO₂gas. However, it was not possible to obtain the current versus concentration curve due to the gas molecules' aggressive chemisorption. However, the device could perform well (with a hysteresis error of ∼10%) for detecting NO gas (which has the 2nd best absolute response after NO₂). These results indicate that the ratio of metal ions in the MOF directly influences the sensing capabilities. Hence, rational synthetic variations in the metal content in MOF can lead to the design and develop highly selective and sensitive chemiresistive sensors.