Biosorption of hexavalent chromium from aqueous solution by pristine and CaCl₂-modified erythromycin production...

In this study, the adsorptive removal of hexavalent chromium [Cr(VI)] from aqueous solutions by the pristine and salt-treated (CaCl₂) erythromycin production residue (EPRs and SEPRs) were investigated. Batch experiments were carried out to determine the effect of contact time, sorbent dosage, pH, initial Cr concentration, and temperature on Cr(VI) sorption by EPRs and SEPRs. The highest adsorptive removal capacities were achieved at the pH equal to 1.0, and the maximum adsorption capacities for EPRs and SEPRs at optimized conditions were 21.74 and 35.24 mg g^-1, respectively. The FTIR spectra and SEM studies were examined for the pristine adsorbent and after the adsorption of Cr(VI). Moreover, thermodynamic results indicated that Cr sorption by EPR/SERPs was feasible, spontaneous, and endothermic under the optimum conditions. Langmuir model fitted well with the experimental data. Kinetic modeling revealed that the biosorption of Cr(VI) by EPRs and SEPRs obeyed the second-order model than the first-order model. The process involving rate-controlling step is much complex involving both boundary layer and intra-particle diffusion processes. Furthermore, the adsorption-coupled-reduction process was believed as the main mechanism of Cr(VI) removal by EPRs and SEPRs. In summary, both adsorbents could be considered as promising low-cost biosorbent for the removal of Cr(VI) from aqueous systems.