Polyaniline coated MOF-derived Mn₂O₃ nanorods for efficient hybrid capacitive deionization

Mn-based oxides are efficient pseudocapacitive electrode materials and have been investigated for capacitive deionization (CDI). However, their poor conductivity seriously affects their desalination performance. In this work, polyaniline coated Mn₂O₃ nanorods (PANI/Mn₂O₃) are synthesized by oxidizing a Mn-based metal organic framework (MOF) and subsequent in-situ chemical polymerization. The polyaniline not only acts as a conductive network for faradaic reactions of Mn₂O₃, but also enhances the desalination rate. PANI/Mn₂O₃ has a specific capacitance of 87 F g^-1 (at 1 A g^-1), superior to that of Mn₂O₃ nanorod (52 F g^-1 at 1 A g^-1). The hybrid CDI cell constructed with a PANI/Mn₂O₃ cathode and an active carbon anode shows a high desalination capacity of 21.6 mg g^-1, superior recyclability with only 11.3% desalination capacity decay after 30 desalination cycles and fast desalination rate of 2.2 mg g^-1 min^-1. PANI/Mn₂O₃ is a potential candidate for high performance CDI applications.