Highly Efficient I₂ Sorption, CO₂ Capture, and Catalytic Conversion by Introducing Nitrogen Donor Sites in a...

Recently, the development of porous absorbents for efficient CO₂ and I₂ capture has attracted considerable attention because of severe global climate change and environmental issues with the nuclear energy. Hence, a unique porous metal-organic framework (MOF), {[Co(L)]·DMF·2H₂O} (1, DMF = N,N-dimethylformamide) with uncoordinated N atoms was rationally constructed via using a heterofunctional 4,6-bis(4'-carboxyphenyl)pyrimidine (H₂L) linker. Interestingly, 1 exhibits exceptional properties for I₂ sorption, CO₂ capture, and catalytic conversion. Particularly, I₂ can be efficiently removed in both vapor and solution forms, and the adsorption amount can reach 676.25 and 345.28 mg g^-1, respectively. Furthermore, complex 1 displays high adsorption capacity for CO₂ (53.78 cm³ g^-1, 273 K). Consequently, 1 is expected to be a promising and practical material for environmental purification due to its excellent adsorption properties.